CO2 has been studied long and hard and is well understood. The evidence for co2 warming is well measured in data.
The greenhouse effect occurs because greenhouse gases let sunlight (shortwave radiation) pass through the atmosphere. The earth absorbs sunlight, warms then reradiates heat (infrared or longwave radiation). The outgoing longwave radiation is absorbed by greenhouse gases in the atmosphere. This heats the atmosphere which in turn re-radiates longwave radiation in all directions. Some of it makes its way back to the surface of the earth. So with more carbon dioxide in the atmosphere, we expect to see less longwave radiation escaping to space at